Skripsi

INTERKALASI HIDROKSI LAPIS GANDA DENGAN SENYAWA POLIOKSOMETALAT H3[α-PW12O40].nH2O dan APLIKASINYA SEBAGAI ADSORBEN CONGO RED

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Penilaian

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Intercalation of polyoxometalate H3[α-PW12O40]·nH2O on layered double hydroxide by comparison weight rasio of layered double hydroxide : polyoxometalate H3[α-PW12O40]·nH2O, i.e: 1:1, 1:2, 1:3 and 1: 4 has been done. The results intercalated layered double hydroxide was characterized using FT-IR spectrophotometer, XRD and TG-DTA analysis. The research results using FT-IR spectrophotometer characterization shown the process of intercalation was not optimum for every weight ratio. Characterization using XRD showed the process of intercalation optimum at ratio (2: 1) that indicated the field (00l) consisting of reflection at (003), (006) and (110)were observed in the area 2θat 60o-63oshown layer double hydroxide were intercalated with polyoxometalate compound. Advanced characterization using TG-DTA analysis at comparison (2:1) showed loss of OH in the layer at 170 to 220°C and for the decomposition of the compounds polioksometalateH3[α-PW12O40]·nH2O at 300 to 400°C. The adsorption process of layered double hydroxide intercalated polioksometalat H3[α-PW12O40]·nH2Oat ratio (2: 1) shows the adsorption rate (k) of 0.81 min-1, the largest adsorption capacity (b) at 70°C is 5,42 mol/g, the largest adsorption energy at 70oC which is 0.6 kJ/mol. The value of the enthalpy (ΔH) and entropy (ΔS) decreased with increasing concentrations of the dye congo red. Effect of pH on the adsorption at pH 8 show the biggest of number congo red adsorbed is 38.1 mg/L.

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Availability

Inventory Code	Barcode	Call Number	Location	Status
1707000734	T18711	T187112017	Central Library (REFERENCES)	Available but not for loan - Not for Loan

Detail Information

Series Title

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Call Number

T187112017

Publisher

Inderalaya : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Sriwijaya., 2017

Collation

xvii, 122 hlm.; ill.; tab.; 20 cm.

Language

Indonesia

ISBN/ISSN

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Classification

572.6

Content Type

Text

Media Type

unmediated

Carrier Type

unspecified

Edition

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Subject(s)

Jurusan Kimia
Komponen protein

Specific Detail Info

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Statement of Responsibility

Furika

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